Compare Fluorine vs Chlorine: Periodic Table Element Comparison Table and Properties
Compare the elements Fluorine and Chlorine on the basis of their properties, attributes and periodic table facts. Compare elements - Fluorine and Chlorine comparison table side by side across over 90 properties. All the elements of similar categories show a lot of similarities and differences in their chemical, atomic, physical properties and uses. These similarities and dissimilarities should be known while we study periodic table elements. You can study the detailed comparison between Fluorine vs Chlorine with most reliable information about their properties, attributes, facts, uses etc. You can compare F vs Cl on more than 90 properties like electronegativity, oxidation state, atomic shells, orbital structure, Electronaffinity, physical states, electrical conductivity and many more. This in-depth comparison helps students, educators, researchers, and science enthusiasts understand the differences and similarities between Fluorine and Chlorine.
Fluorine and Chlorine Comparison
Here's a detailed comparison between Fluorine (F) and Chlorine (Cl), focusing on their position in the periodic table, physical and chemical properties, stability, and uses.
Facts - Basic Element Details
| Name | Fluorine | Chlorine |
|---|---|---|
| Atomic Number | 9 | 17 |
| Atomic Symbol | F | Cl |
| Atomic Weight | 18.9984032 | 35.453 |
| Phase at STP | Gas | Gas |
| Color | Colorless | Yellow |
| Metallic Classification | Halogens | Halogens |
| Group in Periodic Table | group 17 | group 17 |
| Group Name | fluorine family | fluorine family |
| Period in Periodic Table | period 2 | period 3 |
| Block in Periodic Table | p -block | p -block |
| Electronic Configuration | [He] 2s2 2p5 | [Ne] 3s2 3p5 |
| Electronic Shell Structure (Electrons per shell) | 2, 7 | 2, 8, 7 |
| Melting Point | 53.5 K | 171.6 K |
| Boiling Point | 85.03 K | 239.11 K |
| CAS Number | CAS7782-41-4 | CAS7782-50-5 |
| Neighborhood Elements | Neighborhood Elements of Fluorine | Neighborhood Elements of Chlorine |
History
| Parameter | Fluorine | Chlorine |
|---|---|---|
| History | The element Fluorine was discovered by A.-M. Ampère in year 1810 in France. Fluorine derived its name from the Latin fluere, meaning 'to flow'. | The element Chlorine was discovered by W. Scheele in year 1774 in Sweden. Chlorine derived its name from the Greek word chloros, meaning 'greenish yellow'. |
| Discovery | A.-M. Ampère (1810) | W. Scheele (1774) |
| Isolated | H. Moissan (1886) | W. Scheele (1774) |
Presence: Abundance in Nature and Around Us
Parts per billion (ppb) by weight / by atoms (1ppb =10^-7 %)
| Property | Fluorine | Chlorine |
|---|---|---|
| Abundance in Universe | 400 / 30 | 1000 / 40 |
| Abundance in Sun | 500 / 30 | 8000 / 300 |
| Abundance in Meteorites | 89000 / 96000 | 380000 / 160000 |
| Abundance in Earth's Crust | 540000 / 590000 | 170000 / 100000 |
| Abundance in Oceans | 1300 / 420 | 19870000 / 3470000 |
| Abundance in Humans | 37000 / 12000 | 1200000 / 210000 |
Crystal Structure and Atomic Structure
| Property | Fluorine | Chlorine |
|---|---|---|
| Atomic Volume | 11.202 cm3/mol | 22.4129 cm3/mol |
| Atomic Radius | 42 pm | 79 pm |
| Covalent Radius | 71 pm | 99 pm |
| Van der Waals Radius | 147 pm | 175 pm |
Atomic Spectrum - Spectral Lines | ||
| Emission Spectrum |  |  |
| Absorption Spectrum |  |  |
| Lattice Constant | 550, 328, 728 pm | 622.35, 445.61, 817.85 pm |
| Lattice Angle | π/2, π/2, π/2 | π/2, π/2, π/2 |
| Space Group Name | C12/c1 | Cmca |
| Space Group Number | 15 | 64 |
| Crystal Structure | Base Centered Monoclinic  | Base Centered Orthorhombic  |
Atomic and Orbital Properties
| Property | Fluorine | Chlorine |
|---|---|---|
| Atomic Number | 9 | 17 |
| Number of Electrons (with no charge) | 9 | 17 |
| Number of Protons | 9 | 17 |
| Mass Number | 18.9984032 | 35.453 |
| Number of Neutrons | 10 | 18 |
| Shell structure (Electrons per energy level) | 2, 7 | 2, 8, 7 |
| Electron Configuration | [He] 2s2 2p5 | [Ne] 3s2 3p5 |
| Valence Electrons | 2s2 2p5 | 3s2 3p5 |
| Oxidation State | -1 | -1, 1, 3, 5, 7 |
| Atomic Term Symbol (Quantum Numbers) | 2P3/2 | 2P3/2 |
| Shell structure |  |  |
Isotopes and Nuclear Properties
Fluorine has 1 stable naturally occuring isotopes while Chlorine has 2 stable naturally occuring isotopes.
| Parameter | Fluorine | Chlorine |
|---|---|---|
| Known Isotopes | 14F, 15F, 16F, 17F, 18F, 19F, 20F, 21F, 22F, 23F, 24F, 25F, 26F, 27F, 28F, 29F, 30F, 31F | 28Cl, 29Cl, 30Cl, 31Cl, 32Cl, 33Cl, 34Cl, 35Cl, 36Cl, 37Cl, 38Cl, 39Cl, 40Cl, 41Cl, 42Cl, 43Cl, 44Cl, 45Cl, 46Cl, 47Cl, 48Cl, 49Cl, 50Cl, 51Cl |
| Stable Isotopes | Naturally occurring stable isotopes: 19F | Naturally occurring stable isotopes: 35Cl, 37Cl |
| Neutron Cross Section | 0.0096 | 35.3 |
| Neutron Mass Absorption | 0.00002 | 0.033 |
Chemical Properties: Ionization Energies and electron affinity
| Property | Fluorine | Chlorine |
|---|---|---|
| Valence or Valency | 1 | 5 |
| Electronegativity | 3.98 Pauling Scale | 3.16 Pauling Scale |
| Oxidation State | -1 | -1, 1, 3, 5, 7 |
| Electron Affinity | 328 kJ/mol | 349 kJ/mol |
| Ionization Energies | 1st: 1681 kJ/mol 2nd: 3374.2 kJ/mol 3rd: 6050.4 kJ/mol 4th: 8407.7 kJ/mol 5th: 11022.7 kJ/mol 6th: 15164.1 kJ/mol 7th: 17868 kJ/mol 8th: 92038.1 kJ/mol 9th: 106434.3 kJ/mol | 1st: 1251.2 kJ/mol 2nd: 2298 kJ/mol 3rd: 3822 kJ/mol 4th: 5158.6 kJ/mol 5th: 6542 kJ/mol 6th: 9362 kJ/mol 7th: 11018 kJ/mol 8th: 33604 kJ/mol 9th: 38600 kJ/mol 10th: 43961 kJ/mol 11th: 51068 kJ/mol 12th: 57119 kJ/mol 13th: 63363 kJ/mol 14th: 72341 kJ/mol 15th: 78095 kJ/mol 16th: 352994 kJ/mol 17th: 380760 kJ/mol |
Physical Properties
Fluorine (0.001696 g/cm³) is less dense than Chlorine (0.003214 g/cm³). This means that a given volume of Chlorine will be heavier than the same volume of Fluorine. Chlorine is about 89.5 denser than Fluorine
| Property | Fluorine | Chlorine |
|---|---|---|
| Phase at STP | Gas | Gas |
| Color | Colorless | Yellow |
| Density | 0.001696 g/cm3 | 0.003214 g/cm3 |
| Density (when liquid (at melting point)) | - | - |
| Molar Volume | 11.202 cm3/mol | 22.4129 cm3/mol |
Mechanical and Hardness Properties
| Property | Fluorine | Chlorine |
|---|---|---|
Elastic Properties | ||
| Young Modulus | - | - |
| Shear Modulus | - | - |
| Bulk Modulus | - | 1.1 GPa |
| Poisson Ratio | - | - |
Hardness - Tests to Measure of Hardness of Element | ||
| Mohs Hardness | - | - |
| Vickers Hardness | - | - |
| Brinell Hardness | - | - |
Thermal and Electrical Conductivity
| Property | Fluorine | Chlorine |
|---|---|---|
Heat and Conduction Properties | ||
| Thermal Conductivity | 0.0277 W/(m K) | 0.0089 W/(m K) |
| Thermal Expansion | - | - |
Electrical Properties | ||
| Electrical Conductivity | - | 0.01 S/m |
| Resistivity | - | 100 m Ω |
| Superconducting Point | - | - |
Magnetic and Optical Properties
| Property | Fluorine | Chlorine |
|---|---|---|
Magnetic Properties | ||
| Magnetic Type | - | Diamagnetic |
| Curie Point | - | - |
| Mass Magnetic Susceptibility | - | -7.2e-9 m3/kg |
| Molar Magnetic Susceptibility | - | -5.11e-10 m3/mol |
| Volume Magnetic Susceptibility | - | -2.31e-8 |
Optical Properties | ||
| Refractive Index | 1.000195 | 1.000773 |
Acoustic Properties | ||
| Speed of Sound | - | 206 m/s |
Thermal Properties - Enthalpies and thermodynamics
| Property | Fluorine | Chlorine |
|---|---|---|
| Melting Point | 53.5 K | 171.6 K |
| Boiling Point | 85.03 K | 239.11 K |
| Critical Temperature | 144.13 K | 416.9 K |
| Superconducting Point | - | - |
Enthalpies | ||
| Heat of Fusion | 0.26 kJ/mol | 3.2 kJ/mol |
| Heat of Vaporization | 3.27 kJ/mol | 10.2 kJ/mol |
| Heat of Combustion | - | - |
Regulatory and Health - Health and Safety Parameters and Guidelines
| Parameter | Fluorine | Chlorine |
|---|---|---|
| CAS Number | CAS7782-41-4 | CAS7782-50-5 |
| RTECS Number | RTECSLM6475000 | RTECSFO2100000 |
| DOT Hazard Class | 2.3 | - |
| DOT Numbers | 9192 | 1017 |
| EU Number | EU231-954-8 | - |
| NFPA Fire Rating | 0 | - |
| NFPA Health Rating | 4 | - |
| NFPA Reactivity Rating | 4 | - |
| NFPA Hazards | Oxidizing Agent, Water Reactive | - |
| AutoIgnition Point | - | - |
| Flashpoint | - | - |
Compare Fluorine and Chlorine With Other Elements
Compare Fluorine and Chlorine with other elements of the periodic table. Explore howFluorine and Chlorine stack up against other elements of the periodic table. Use our interactive comparison tool to analyze 90+ properties across different metals, non-metals, metalloids, and noble gases. Understanding these differences is crucial for applications in engineering, chemistry, electronics, biology, and material science.
Compare Fluorine with all Group 17 elementsCompare Fluorine with AstatineCompare Fluorine with BromineCompare Fluorine with ChlorineCompare Fluorine with IodineCompare Fluorine with Tennessine Compare Fluorine with all Period 2 elementsCompare Fluorine with BerylliumCompare Fluorine with BoronCompare Fluorine with CarbonCompare Fluorine with NitrogenCompare Fluorine with NeonCompare Fluorine with LithiumCompare Fluorine with Oxygen Compare Fluorine with all Halogens elements | Compare Chlorine with all Group 17 elementsChlorine vs Astatine ComparisonChlorine vs Bromine ComparisonChlorine vs Fluorine ComparisonChlorine vs Iodine ComparisonChlorine vs Tennessine Comparison Compare Chlorine with all Period 3 elementsChlorine vs Argon ComparisonChlorine vs Aluminium ComparisonChlorine vs Phosphorus ComparisonChlorine vs Sulfur ComparisonChlorine vs Magnesium ComparisonChlorine vs Silicon ComparisonChlorine vs Sodium Comparison Compare Chlorine with all Halogens elements |